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1 Institute of Soil Science, Chinese Academy of Sciences, 71 Beijing East Road, 210008, Nanjing, China
2 Laboratoire de Géologie, CNRS 2113 Ecole Normale Supérieure, 24 rue Lhomond, 75231 Paris, France
* E-mail address of corresponding author: papa{at}geologie.ens.fr
The loss of K-bearing clay minerals has been observed over an 80 y cultivation period in Chinese rice paddies despite the use of NKP fertilizers. Clay mineral determinations were made in flood-irrigated paddies cultivated for 3, 10, 15, 30 and 80 y in clayey (45 wt.%), red soils derived from red Quaternary sediments. Three clay minerals are initially present in these soils: illite-mica, magnesian chlorite and an interstratified mica-aluminous chlorite mineral. This last phase was identified using computer simulations . The K-bearing phases (discrete mica and illite as well as interstratified mica layers) are to a large extent lost while the Fe content decreases in the soil as a whole and increases in the chlorite. The mica component in the mixed-layer mineral decreases also. These changes in clay mineralogy and relative abundance suggest a loss of potassic minerals and an increase in the formation of less siliceous, more ferro-magnesian chlorite. These changes occur over 30 y or less, a rather rapid, irreversible transformation of soil clay minerals. Such loss of potassic minerals renders the cultivation more dependent on fertilizer amendment.
Key Words: Clay Mineral Irrigation Mica-chlorite Interlayer Potassium
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Y.-l. Liu, B. Zhang, C.-l. Li, F. Hu, and B. Velde Long-Term Fertilization Influences on Clay Mineral Composition and Ammonium Adsorption in a Rice Paddy Soil Soil Sci. Soc. Am. J., September 30, 2008; 72(6): 1580 - 1590. [Abstract] [Full Text] [PDF] |
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