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Clays and Clay Minerals; October 2007; v. 55; no. 5; p. 524-533; DOI: 10.1346/CCMN.2007.0550507
© 2007 Clay Minerals Society
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ZEOLITIZATION OF TUFFS AT QUINAMÁVIDA, CENTRAL SOUTHERN CHILE

Sophía Bascuñan, Ursula Kelm*, Vilma Sanhueza and Guillermo Alfaro

Instituto de Geología Económica Aplicada, Universidad de Concepción, Casilla 160-C, Concepción, Chile

* E-mail address of corresponding author: ukelm{at}udec.cl

Tuffs of the Tertiary Colbún Formation near Quinamávida in central southern Chile have been mapped and their mineralogy analyzed. The pyroclastic rocks present a maximum outcropping thickness of 120 m and are dominated by vitreous lapilli and minor lithic tuffs, the products of active volcanism nearby. About 10% of the tuffs consist of lenses of fine banded tuffs with a high leaf content that were deposited in shallow lakes during quiescent periods between periods of volcanic activity. This tuff sequence is pervasively transformed to clinoptilolite/heulandite and mordenite with variable amounts of plagioclase, minor quartz and smectite. Factors thought to have influenced this conversion to zeolites are a humid climate following deposition combined with a slightly elevated heat flow. Local hydrogeological conditions have modified the cation-hydrogen ion ratios across the study area favoring the formation of clinoptilolite/heulandite and mordenite with medium-minor smectite in the center and south, and a more abundant presence of smectite in the north of the study area.

Key Words: Chile • Heulandite • Clinoptilolite • Mordenite • Tuff • Zeolite







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